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Elements
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Elements; September 2005; v. 1; no. 4; p. 211-216; DOI: 10.2113/gselements.1.4.211
© 2005 Mineralogical Society of America
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Shining Light on Metals in the Environment

David H. McNear, Jr., Ryan Tappero and Donald L. Sparks

Environmental Soil Chemistry Research Group
Department of Plant and Soil Sciences, 152 Townsend Hall
University of Delaware, Newark, DE 19717-1303, USA

Correspondence: Corresponding author: dlsparks{at}udel.edu

Elucidating the speciation of heavy metals in the environment is paramount to understanding their potential mobility and bioavailability. Cutting-edge synchrotron-based techniques such as microfocused X-ray absorption fine-structure (XAFS) and X-ray fluorescence (XRF) spectroscopy and microtomography have revolutionized the way metal reactions and processes in natural systems are studied. In this article, we apply these intense-light tools to decipher metal forms (species) and associations in contaminated soils and metal-hyperaccumulating plants.

KEYWORDS: X-ray absorption fine-structure spectroscopy (XAFS), metal-hyperaccumulator plants, metal speciation







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